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Essay by   •  January 12, 2011  •  519 Words (3 Pages)  •  1,209 Views

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The electronic structure has been proposed as 1sO2.00 2sO1.82 2pxO1.50 2pzO1.12 2pyO2.00 1sH10.78 1sH20.78 [71], however it now appears that the 2s orbital may be effectively unhybridized with the bond angle expanded from the (then) expected angle of 90Ð'o due to the steric and ionic repulsion between the partially-positively charged hydrogen atoms (as proposed by Pauling over 50 years ago [99]). The molecular orbitals of water, (1a1)2(2a1)2(1b2)2(3a1)2(1b1)2, are shown on another page (24 KB).

The electronic structure has been proposed as 1sO2.00 2sO1.82 2pxO1.50 2pzO1.12 2pyO2.00 1sH10.78 1sH20.78 [71], however it now appears that the 2s orbital may be effectively unhybridized with the bond angle expanded from the (then) expected angle of 90Ð'o due to the steric and ionic repulsion between the partially-positively charged hydrogen atoms (as proposed by Pauling over 50 years ago [99]). The molecular orbitals of water, (1a1)2(2a1)2(1b2)2(3a1)2(1b1)2, are shown on another page (24 KB).

The electronic structure has been proposed as 1sO2.00 2sO1.82 2pxO1.50 2pzO1.12 2pyO2.00 1sH10.78 1sH20.78 [71], however it now appears that the 2s orbital may be effectively unhybridized with the bond angle expanded from the (then) expected angle of 90Ð'o due to the steric and ionic repulsion between the partially-positively charged hydrogen atoms (as proposed by Pauling over 50 years ago [99]). The molecular orbitals of water, (1a1)2(2a1)2(1b2)2(3a1)2(1b1)2, are shown on another page (24 KB).

The electronic structure has been proposed as 1sO2.00 2sO1.82 2pxO1.50 2pzO1.12 2pyO2.00 1sH10.78 1sH20.78 [71], however it now appears that the 2s orbital may be effectively unhybridized with the bond angle expanded from the (then) expected angle of 90Ð'o due to the steric and ionic repulsion between the partially-positively charged hydrogen atoms (as proposed by Pauling over 50 years ago [99]). The molecular orbitals of water, (1a1)2(2a1)2(1b2)2(3a1)2(1b1)2, are shown on another page (24 KB).

The electronic structure has been proposed as 1sO2.00 2sO1.82 2pxO1.50 2pzO1.12

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